Thermal and Fire Behavior of a Bio-Based Epoxy/Silica Hybrid Cured with Methyl Nadic Anhydride

thermosetting polymers have been widely used in various industrial applications as adhesives, coatings and laminated materials, among others. More recently, bisphenol A (BPA) have been banned as a raw material polymer product, because the harmful effects on human health. On the other hand, the use of aromatic amines as curing agents confer the properties of heat resistance, mechanical and fire very well for the final product, even though they are toxic and are subject to government restrictions. In this context, diepoxy monomer anhydride derived sugar and green represent a sustainable alternative to BPA and aromatic amines. Here, we report the “in-situ” sol-gel synthesis, using as a precursor tetraethylorthosilicate (TEOS) and aminopropyl triethoxysilane (APTS) to obtain bio-based epoxy / silica composite;

The first step, APTS is left to react with 2,5-bis [(oxyran-2-ylmethoxy) methyl] furan (BOMF) or diglycidyl ether of bisphenol A (DGEBA) monomer, and the resulting silica particles in epoxy in a second step ; The second system nadic cured with methyl anhydride (MNA). composite morphology investigation through a transmission electron microscope (TEM) showed that the hybrid strategy enables excellent distribution of silica nanoparticles (at the nanometric level) to be achieved in a hybrid network structure for the second diepoxy monomer. Regarding the behavior of the fire, as assessed in a vertical flame spread test, the use of preservatives prevented anhydride melt dripping phenomenon and provide high char-forming character to the bio-based epoxy systems and analog phenyl them.

In addition, forced combustion tests showed that the use of anhydride hardener is not the result of an aliphatic polyamine remarkable decline of the rate of heat release. An overall decline of smoke parameters, which is highly desirable in the context of a larger fire safety observed in the case of system BOMF / MNA. The experimental results show that the effect of silica nanoparticles on the fire behavior seems to be related to the level of their dispersion.

 Thermal and Fire Behavior of a Bio-Based Epoxy/Silica Hybrid Cured with Methyl Nadic Anhydride
Thermal and Fire Behavior of a Bio-Based Epoxy/Silica Hybrid Cured with Methyl Nadic Anhydride

methacrylate perspective in the current dental practices

Objective: To provide a current perspective on the sensitivity of dental personnel with methacrylate materials.


Overview: Methacrylate related sensitivities and allergies today goes beyond traditional thinking about denture base resins and materials while methyl methacrylate. Methacrylate now ubiquitous in the current dental practice and dental personnel should be aware that dental adhesives contain potent sensitizer may also be cross-sensitization to methacrylates individuals did not experience. Sensitivity grow to 2-hydroxyethyl methacrylate (HEMA) has described an epidemic in nature because the industry of artificial nails with dental patients and dental personnel may be more susceptible to tooth methacrylate sensitization.

While contact dermatitis remains the most common clinical presentation related methacrylate, respiratory complications and asthma increase is associated with exposure to methacrylates. While additional personal protective equipment (PPE) is expected to be the first protective choice, the National Institute for Occupational Safety and Health (NIOSH) considers the overall PPE largely ineffective and should be considered only as a last resort.


Conclusion: Dental personnel must be aware of the source of methacrylate and control measures limit the use of workplace exposure to second methacrylate dental personnel and patients.

AAV (Intact) Antibody

abx021503-005mg 0.05 mg
EUR 1387.2

TSH Intact Antibody

abx023630-1mg 1 mg
EUR 693.6

TSH (intact) Antibody

abx022896-05mg 0.5 mg
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TSH intact Antibody

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TSH (intact) antibody

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EUR 239
Description: Affinity purified Goat polyclonal TSH (intact) antibody

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GWB-9A4CE0 1 mg Ask for price

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abx023630-400l 400 µl Ask for price

TSH Intact Antibody

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FSH (intact) Antibody

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FSH (intact) Antibody

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TSH intact Antibody

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Anti- Parathyroid Hormone (PTH) Intact Antibody

GWB-EEDCD6 0.1 ml Ask for price

Anti- Parathyroid Hormone (PTH) Intact Antibody

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intact hCG Antibody

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EUR 710.4

AAV antibody (intact)

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EUR 906
Description: Mouse monoclonal AAV antibody (intact)

AAV antibody (intact)

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EUR 463.2
Description: Mouse monoclonal AAV intact particle antibody

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Description: Affinity purified goat polyclonal hCG antibody

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GWB-1582DA 1 ml Ask for price

AAV Antibody (intact)

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AAV antibody (intact)

MBS830678-5mL 5mL
EUR 460

AAV antibody (intact)

MBS830678-5x5mL 5x5mL
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AAV antibody (intact)

MBS530792-005mg 0.05mg
EUR 1415

AAV antibody (intact)

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OAMA00658-1MG - TSH intact Antibody

OAMA00658-1MG 1mg
EUR 449

TSH intact & beta Antibody

abx021318-1mg 1 mg
EUR 693.6

TSH intact & beta Antibody

abx021319-1mg 1 mg
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TSH intact & beta Antibody

abx021320-1mg 1 mg
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TSH intact & beta Antibody

abx021319-400l 400 µl Ask for price

TSH intact & beta Antibody

abx021319-80l 80 µl
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TSH intact & beta Antibody

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TSH intact & beta Antibody

abx021320-80l 80 µl
EUR 637.5

Luteinizing Hormone (LH) Intact, Antibody

GWB-1BB791 1 mg Ask for price

Luteinizing Hormone (LH) Intact, Antibody

GWB-6CEE4B 1 mg Ask for price

AAV antibody (intact) (biotin)

61R-1011 750 uL
EUR 637
Description: Mouse monoclonal AAV intact particle antibody (biotin)

AAV antibody (intact) (biotin)

MBS830078-075mL 0.75mL
EUR 810

AAV antibody (intact) (biotin)

MBS830078-5x075mL 5x0.75mL
EUR 3495

Anti-Cryptosporidium Parvum (Intact Oocysts) Antibody

MBS4159273-01mg 0.1mg
EUR 635

Anti-Cryptosporidium Parvum (Intact Oocysts) Antibody

MBS4159273-5x01mg 5x0.1mg
EUR 2610

Mouse Anti Human Fsh Intact Monoclonal Antibody

CABT-49125MH 0.5 mg
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AAV5 (intact particle) antibody

10R-2445 50 ug
EUR 1081
Description: Mouse monoclonal AAV 5 (intact particle) antibody

AAV1 (intact particle) antibody

10R-2446 50 ug
EUR 884
Description: Mouse monoclonal AAV 1 (intact particle) antibody

AAV5 (intact particle) antibody

10R-2494 500 ul
EUR 1101.6
Description: Mouse monoclonal AAV 5 (intact particle) antibody

SHEEP ANTI hCG (INTACT)

MBS220742-1mL 1mL
EUR 365

SHEEP ANTI hCG (INTACT)

MBS220742-5x1mL 5x1mL
EUR 1465

Intact Complement C4 (C4) Antibody

abx025027-400l 400 µl
EUR 518.75

Human Chorionic Gonadotropin (hCG) intact Antibody

GWB-T00626 1 mg Ask for price

Mouse monoclonal Intact hCG antibody

MBS5306263-1mg 1mg
EUR 385

Mouse monoclonal Intact hCG antibody

MBS5306263-5x1mg 5x1mg
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Anti-AAV6 (intact particle) monoclonal antibody, clone BEL7

CABT-B9064 50 µg
EUR 1039.5
Description: Mouse

Anti-AAV8 (intact particle) monoclonal antibody, clone BEL9

CABT-B9065 50 µg
EUR 1029
Description: Mouse

Anti-AAV9 (intact particles) monoclonal antibody, clone BEL0

DPAB-AV01 0.2 ml
EUR 561.75
Description: Mouse

Anti-AAV5 (intact particle) monoclonal antibody, Clone BEL6b

DMAB6353 50 µg
EUR 892.5
Description: Mouse

Brucella Abortus, Intact Cells Antibody

abx021561-1mg 1 mg
EUR 961.2

Brucella Abortus, Intact Cells Antibody

abx021562-1mg 1 mg
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Brucella abortus Antibody (intact cells)

GWB-1DA290 1 mg Ask for price

Brucella abortus Antibody (intact cells)

GWB-8ABE86 1 mg Ask for price

Affinity purified Goat polyclonal TSH (intact) antibody

MBS5305018-05mg 0.5mg
EUR 440

Affinity purified Goat polyclonal TSH (intact) antibody

MBS5305018-5x05mg 5x0.5mg
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MOUSE ANTI HUMAN FSH INTACT

MBS212975-05mg 0.5mg
EUR 625

MOUSE ANTI HUMAN FSH INTACT

MBS212975-5x05mg 5x0.5mg
EUR 2630

Human Anti-AAV2 (intact particle) Monoclonal antibody, clone B31

CABT-R9062L 100 μg
EUR 880
Description: Human

Human Anti-AAV5 (intact particle) Monoclonal antibody, clone F56

DMAB-CS23065 50 ug, 100 ug, 1 mg Ask for price
Description: Humanized

Human Anti-AAV8 (intact particle) Monoclonal antibody, clone BEL9

CABT-LY254 100 μg
EUR 880
Description: Human

Human Anti-AAV6 (intact particle) Monoclonal antibody,clone BEL7

CABT-R9064L 50 μg, 100 μg, 1 mg Ask for price
Description: Human

Human Anti-AAV9 (intact particles) Monoclonal antibody, clone BEL0

CABT-L21Y197 100 μg
EUR 880
Description: Human

Anti-AAV8/9 (intact particle) monoclonal antibody, clone BEL9/0

CABT-B9066 5 ml
EUR 1037.4
Description: Mouse

Goat anti-HCG (intact) - Affinity Pure

MBS686002-1mg 1mg
EUR 300

Goat anti-HCG (intact) - Affinity Pure

MBS686002-5x1mg 5x1mg
EUR 1210

Goat anti-TSH (intact) - Affinity Pure

MBS686032-05mg 0.5mg
EUR 260

Goat anti-TSH (intact) - Affinity Pure

MBS686032-5x05mg 5x0.5mg
EUR 1025

Adeno Associated Virus (AAV) Intact particles, Antibody

GWB-7ACA46 0.05 mg Ask for price

OAMA00390-1MG - Brucella abortus intact cells Antibody

OAMA00390-1MG 1mg
EUR 649

OAMA00394-1MG - Brucella abortus intact cells Antibody

OAMA00394-1MG 1mg
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FSH beta (FSHB) (intact) sheep polyclonal antibody, Serum

AP05420SU-N 100 µl Ask for price

Mouse antibody for Neisseria gonorrhoeae intact bacteria

6142 100 ug
EUR 386.26
Description: This is purified Mouse monoclonal antibody against Neisseria gonorrhoeae intact bacteria for WB, ELISA.

Mouse antibody for Neisseria gonorrhoeae intact bacteria

6144 100 ug
EUR 386.26
Description: This is purified Mouse monoclonal antibody against Neisseria gonorrhoeae intact bacteria for WB, ELISA.

Mouse antibody for Neisseria gonorrhoeae intact bacteria

6145 100 ug
EUR 386.26
Description: This is purified Mouse monoclonal antibody against Neisseria gonorrhoeae intact bacteria for WB, ELISA.

Rat Intact Parathormone (Intact PTH) CLIA Kit

abx197171-100l 100 µl Ask for price

Rat Intact Parathormone (Intact PTH) CLIA Kit

abx197171-50l 50 µl
EUR 618.75

Rat Intact Parathormone (Intact PTH) ELISA Kit

abx255779-96tests 96 tests
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Mouse Intact Parathormone (Intact PTH) CLIA Kit

abx197170-100l 100 µl Ask for price

Mouse Intact Parathormone (Intact PTH) CLIA Kit

abx197170-50l 50 µl
EUR 618.75

Mouse Intact Parathormone (Intact PTH) ELISA Kit

abx254234-96tests 96 tests
EUR 904.8

GOAT ANTI CAT IGG, INTACT IGG, HRP, 2 ML

9450074 1ML
EUR 212.04

GOAT ANTI RAT IGG, INTACT IGG, HRP, 2 ML

9451124 1ML
EUR 207.65

Monoclonal Antibody to Human Chorionic Gonadotropin- Intact (hCG)

MBS410062-1mg 1mg
EUR 445

GOAT ANTI CAT IGG, INTACT IGG, FITC, 2 MG

9450073 1MG
EUR 181.29

GOAT ANTI RAT IGG, INTACT IGG, FITC, 2 MG

9451123 1MG
EUR 169.58

RABBIT ANTI DOG IGG, INTACT IGG, HRP, 1.5 ML

9450124 1ML
EUR 250.11

GOAT ANTI HORSE IGG, INTACT IGG, HRP, 2 ML

9450344 1ML
EUR 212.04

GOAT ANTI HUMAN IGG, INTACT IGG, HRP, 2 ML

9450434 1ML
EUR 216.43

GOAT ANTI MOUSE IGG, INTACT IGG, HRP, 2 ML

9450714 1ML
EUR 207.65

GOAT ANTI MOUSE IGM , INTACT IGG, HRP, 2 ML

9450974 1ML
EUR 317.46

RABBIT ANTI RAT IGG, INTACT IGG, HRP, 1.5 ML

9451174 1ML
EUR 235.47

PTH intact

DE3645 96
EUR 346

GOAT ANTI BOVINE IGG, INTACT IGG, HRP, 2 ML

9450014 1ML
EUR 212.04

GOAT ANTI CAT IGG, INTACT IGG, UNCONJ., 2 MG

9450070 1MG
EUR 153.48

GOAT ANTI CAT IGG, INTACT IGG, BIOTIN, 2 ML

9450072 1ML
EUR 212.04

RABBIT ANTI DOG IGG, INTACT IGG, FITC, 1.5 MG

9450123 1MG
EUR 190.08

DONKEY ANTI GOAT IGG, INTACT IGG, HRP, 1 ML

9450134 1ML
EUR 198.86

RABBIT ANTI GOAT IGG, INTACT IGG, HRP, 1.5 ML

9450164 1ML
EUR 228.15

GOAT ANTI HORSE IGG, INTACT IGG, FITC, 2 MG

9450343 1MG
EUR 181.29

GOAT ANTI HUMAN IGG, INTACT IGG, FITC, 2 MG

9450433 1MG
EUR 275

GOAT ANTI MOUSE IGG, INTACT IGG, FITC, 2 MG

9450713 1MG
EUR 169.58

SHEEP ANTI MOUSE IGG, INTACT IGG, HRP, 2 ML

9450814 1ML
EUR 207.65

GOAT ANTI MOUSE IGM , INTACT IGG, FITC, 2 MG

9450973 1MG
EUR 258.89

GOAT ANTI RABBIT IGG, INTACT IGG, HRP, 2 ML

9451034 1ML
EUR 207.65

GOAT ANTI RAT IGG, INTACT IGG, UNCONJ., 2 MG

9451120 1MG
EUR 153.48

GOAT ANTI RAT IGG, INTACT IGG, BIOTIN, 2 ML

9451122 1ML
EUR 207.65

RABBIT ANTI RAT IGG, INTACT IGG, FITC, 1.5 MG

9451173 1MG
EUR 169.58

GOAT ANTI BOVINE IGG, INTACT IGG, FITC, 2 MG

9450013 1MG
EUR 181.29

DONKEY ANTI GOAT IGG, INTACT IGG, FITC, 1 MG

9450133 1MG
EUR 152.01

RABBIT ANTI GOAT IGG, INTACT IGG, FITC, 1.5 MG

9450163 1MG
EUR 169.58

RABBIT ANTI HORSE IGG, INTACT IGG, HRP, 1.5 ML

9450364 1ML
EUR 250.11

RABBIT ANTI HUMAN IGG, INTACT IGG, HRP, 1.5 ML

9450514 1ML
EUR 258.89

RABBIT ANTI MOUSE IGG, INTACT IGG, HRP, 1.5 ML

9450764 1ML
EUR 235.47

SHEEP ANTI MOUSE IGG, INTACT IGG, FITC, 2 MG

9450813 1MG
EUR 169.58

GOAT ANTI RABBIT IGG, INTACT IGG, FITC, 2 MG

9451033 1MG
EUR 169.58

RABBIT ANTI SHEEP IGG, INTACT IGG, HRP, 1.5 ML

9451274 1ML
EUR 228.15

RABBIT ANTI BOVINE IGG, INTACT IGG, HRP, 1.5 ML

9450034 1ML
EUR 250.11

RABBIT ANTI DOG IGG, INTACT IGG, UNCONJ., 2 MG

9450120 1MG
EUR 195.94

RABBIT ANTI DOG IGG, INTACT IGG, BIOTIN, 1.5 ML

9450122 1ML
EUR 250.11

GOAT ANTI HORSE IGG, INTACT IGG, UNCONJ., 2 MG

9450340 1MG
EUR 153.48

GOAT ANTI HORSE IGG, INTACT IGG, BIOTIN, 2 ML

9450342 1ML
EUR 212.04

RABBIT ANTI HORSE IGG, INTACT IGG, FITC, 1.5 MG

9450363 1MG
EUR 190.08

GOAT ANTI HUMAN IGG, INTACT IGG, UNCONJ., 2 MG

9450430 1MG
EUR 169.58

GOAT ANTI HUMAN IGG, INTACT IGG, BIOTIN, 2 ML

9450432 1ML
EUR 156.4

RABBIT ANTI HUMAN IGG, INTACT IGG, FITC, 1.5 MG

9450513 1MG
EUR 242.79

GOAT ANTI MOUSE IGG, INTACT IGG, UNCONJ., 2 MG

9450710 1MG
EUR 153.48

GOAT ANTI MOUSE IGG, INTACT IGG, BIOTIN, 2 ML

9450712 1ML
EUR 207.65

RABBIT ANTI MOUSE IGG, INTACT IGG, FITC, 1.5 MG

9450763 1MG
EUR 169.58

GOAT ANTI MOUSE IGM , INTACT IGG, UNCONJ., 2 MG

9450970 1MG
EUR 213.5

GOAT ANTI MOUSE IGM , INTACT IGG, BIOTIN, 2 ML

9450972 1ML
EUR 317.46

RABBIT ANTI RAT IGG, INTACT IGG, UNCONJ., 2 MG

9451170 1MG
EUR 184.22

RABBIT ANTI RAT IGG, INTACT IGG, BIOTIN, 1.5 ML

9451172 1ML
EUR 235.47

RABBIT ANTI SHEEP IGG, INTACT IGG, FITC, 1.5 MG

9451273 1MG
EUR 169.58

Cow Intact Parathyroid Hormone (Intact PTH) ELISA Kit

abx259217-96tests 96 tests
EUR 990

GOAT ANTI BOVINE IGG, INTACT IGG, UNCONJ., 2 MG

9450010 1MG
EUR 153.48

GOAT ANTI BOVINE IGG, INTACT IGG, BIOTIN, 2 ML

9450012 1ML
EUR 212.04

RABBIT ANTI BOVINE IGG, INTACT IGG, FITC, 1.5 MG

9450033 1MG
EUR 190.08

RABBIT ANTI CHICKEN IGY, INTACT IGG, HRP, 1.5 ML

9450104 1ML
EUR 250.11

DONKEY ANTI GOAT IGG, INTACT IGG, UNCONJ., 1 MG

9450130 1MG
EUR 149.08

DONKEY ANTI GOAT IGG, INTACT IGG, BIOTIN, 1 ML

9450132 1ML
EUR 198.86

RABBIT ANTI GOAT IGG, INTACT IGG, UNCONJ., 2 MG

9450160 1MG
EUR 184.22

RABBIT ANTI GOAT IGG, INTACT IGG, BIOTIN, 1.5 ML

9450162 1ML
EUR 228.15

SHEEP ANTI MOUSE IGG, INTACT IGG, UNCONJ., 2 MG

9450810 1MG
EUR 153.48

SHEEP ANTI MOUSE IGG, INTACT IGG, BIOTIN, 2 ML

9450812 1ML
EUR 207.65

GOAT ANTI RABBIT IGG, INTACT IGG, UNCONJ., 2 MG

9451030 1MG
EUR 153.48

GOAT ANTI RABBIT IGG, INTACT IGG, BIOTIN, 2 ML

9451032 1ML
EUR 207.65

RABBIT ANTI CHICKEN IGY, INTACT IGG, FITC, 1.5 MG

9450103 1MG
EUR 190.08

RABBIT ANTI HORSE IGG, INTACT IGG, UNCONJ., 2 MG

9450360 1MG
EUR 195.94

RABBIT ANTI HORSE IGG, INTACT IGG, BIOTIN, 1.5 ML

9450362 1ML
EUR 250.11

RABBIT ANTI HUMAN IGG, INTACT IGG, UNCONJ., 2 MG

9450510 1MG
EUR 169.58

RABBIT ANTI HUMAN IGG, INTACT IGG, BIOTIN, 1.5 ML

9450512 1ML
EUR 191.54

RABBIT ANTI MOUSE IGG, INTACT IGG, UNCONJ., 2 MG

9450760 1MG
EUR 184.22

RABBIT ANTI MOUSE IGG, INTACT IGG, BIOTIN, 1.5 ML

9450762 1ML
EUR 235.47

RABBIT ANTI SHEEP IGG, INTACT IGG, UNCONJ., 2 MG

9451270 1MG
EUR 184.22

RABBIT ANTI SHEEP IGG, INTACT IGG, BIOTIN, 1.5 ML

9451272 1ML
EUR 228.15

GOAT ANTI CAT IGG, INTACT IGG, ALK PHOS, 1 ML

9450071 1ML
EUR 258.89

GOAT ANTI RAT IGG, INTACT IGG, ALK PHOS, 1 ML

9451121 1ML
EUR 258.89

TSH beta (TSHB) (intact) mouse monoclonal antibody, clone B31, Purified

AM31653PU-N 1 mg Ask for price

Cryptosporidium parvum (Intact Oocysts) goat polyclonal antibody, Purified

AP00667PU-N 1 ml Ask for price

RABBIT ANTI BOVINE IGG, INTACT IGG, UNCONJ., 2 MG

9450030 1MG
EUR 195.94

RABBIT ANTI BOVINE IGG, INTACT IGG, BIOTIN, 1.5 ML

9450032 1ML
EUR 250.11

Diphtheria toxin (intact) mouse monoclonal antibody, clone 8G1, Purified

BM953 100 µg Ask for price

RABBIT ANTI CHICKEN IGY, INTACT IGG, UNCONJ., 2 MG

9450100 1MG
EUR 195.94

RABBIT ANTI CHICKEN IGY, INTACT IGG, BIOTIN, 1.5 ML

9450102 1ML
EUR 250.11

RABBIT ANTI DOG IGG, INTACT IGG, ALK PHOS, 1 ML

9450121 1ML
EUR 267.68

GOAT ANTI GUINEA PIG IGG, INTACT IGG, HRP, 2 ML

9450264 1ML
EUR 212.04

GOAT ANTI HORSE IGG, INTACT IGG, ALK PHOS, 1 ML

9450341 1ML
EUR 258.89

GOAT ANTI HUMAN IGG, INTACT IGG, ALK PHOS, 1 ML

9450431 1ML
EUR 207.65

GOAT ANTI MOUSE IGG, INTACT IGG, ALK PHOS, 1 ML

9450711 1ML
EUR 258.89

GOAT ANTI MOUSE IGM , INTACT IGG, ALK PHOS, 1 ML

9450971 1ML
EUR 352.59

RABBIT ANTI RAT IGG, INTACT IGG, ALK PHOS, 1 ML

9451171 1ML
EUR 267.68

GOAT ANTI BOVINE IGG, INTACT IGG, ALK PHOS, 1 ML

9450011 1ML
EUR 258.89

DONKEY ANTI GOAT IGG, INTACT IGG, ALK PHOS, 1 ML

9450131 1ML
EUR 258.89

RABBIT ANTI GOAT IGG, INTACT IGG, ALK PHOS, 1 ML

9450161 1ML
EUR 267.68

GOAT ANTI GUINEA PIG IGG, INTACT IGG, FITC, 2 MG

9450263 1MG
EUR 181.29

SHEEP ANTI MOUSE IGG, INTACT IGG, ALK PHOS, 1 ML

9450811 1ML
EUR 258.89

GOAT ANTI RABBIT IGG, INTACT IGG, ALK PHOS, 1 ML

9451031 1ML
EUR 258.89

FSH beta (FSHB) (intact) mouse monoclonal antibody, clone 090-10264, Purified

BM2498 1 mg Ask for price


Clinical significance: Sensitization to material workplace methacrylate is a major concern grows teeth and dental personnel should be aware of both the content of methacrylic current materials and products that contain ingredients with the most potential for sensitization.